TE WHAKAMĀRAMA TIRITIHIRIHIRIHIRIHIRIHIRIHIRI CAS:5034-06-0

He matū whai hua te Trimethylsulfoxonium chloride i roto i te hanga matū waro, inā koa i roto i te tauhohenga whakapūngao Swern hei huri i ngā waipiro hei aldehydes, hei ketones rānei. He wāhanga matua tēnei matū i roto i te tikanga whakapūngao Swern, i te taha o te oxalyl chloride me te dimethylsulfoxide, e āhei ai te whakapūngao whai hua me te whiriwhiri o ngā waipiro tuatahi me tuarua hei aldehydes me ngā ketones. Ko te whakamahinga o te trimethylsulfoxonium chloride i roto i te tukanga whakapūngao Swern he painga pēnei i ngā āhuatanga tauhohenga ngawari, ngā hua teitei, me te hototahi ki ngā momo rōpū mahi, e waiho ana hei taputapu whai hua i roto i te hanga o ngā ngota waro matatini. Hei tāpiri, ka kitea te whakamahinga o te trimethylsulfoxonium chloride hei kaihoko methylating i roto i te matū waro, e āhei ai te methylation o ngā momo nucleophiles i raro i ngā āhuatanga ngawari. Ka taea e tēnei matū te whakahaere i te whakaurunga o ngā rōpū methyl ki roto i ngā matū waro, e āhei ai te hanga o ngā hua methylated rerekē me ngā hanganga me ngā āhuatanga kua whakaritea. Hei tāpiritanga, ka whakamahia te trimethylsulfoxonium chloride ki te whakarite i ngā α-chloroketones me ngā α-bromoketones, he takawaenga nui i roto i te hanganga rauropi mō ngā panonitanga me te whakaputanga. I roto i te matū rongoā me te kimi rongoā, ka taea te whakamahi i te trimethylsulfoxonium chloride ki te hanga i ngā takawaenga rongoā me ngā matū koiora. Mā te whakauru i tēnei matū ki roto i ngā huarahi hanga, ka taea e ngā kairangahau te uru atu ki te whānuitanga o ngā matū me ngā mahi rongoā pea, ka taea ai te tūhura i ngā kaitono rongoā hou me te whakawhanake i ngā rongoā hou. Ko te kaha o te matū ki te whakarerekē i ngā hanganga ngota ngota me te whakahaere i ngā tauhohenga rauropi matua ka whai wāhi ki te hoahoa me te arotau i ngā ngota ngota me ngā pānga koiora e hiahiatia ana me ngā āhuatanga rongoā. I te nuinga o te wā, he mahi nui tā te trimethylsulfoxonium chloride i roto i te hanganga rauropi, e tuku ana i tētahi taputapu nui ki ngā kaimātai matū hanga mō ngā panonitanga pēnei i te waikura, te methylation, me te whakahaere rōpū mahi. Ko tōna ngāwari ki te whakamahi, ngā āhuatanga tauhohenga ngawari, me te hototahi ki ngā momo matū rerekē ka waiho hei matū nui i roto i te pouaka taputapu a ngā kaimātai matū rauropi me ngā kairangahau e mahi ana i roto i te kitenga rongoā, te matū rongoā, me te hanganga matū.