di-μ-chloro-bis(η-allyl)palladium CAS:12012-95-2

Ko te di-μ-chloro-bis(η-allyl)palladium te mea nui e whakamahia ana i roto i te whakaterenga, inā koa i roto i te wāhanga o te whakakapinga allylic me ngā tauhohenga alkylation allylic. He kaiwhakaoho mō te mahi a ngā hononga allylic CH, e āhei ai te hanganga o ngā hononga waro-waro me te waro-heteroatom hou. He mea nui ēnei tauhohenga i roto i te hanganga o ngā ngota waro matatini, pērā i ngā hua taiao, ngā rongoā, me ngā matū pai. Hei tāpiri, ka whakamahia te di-μ-chloro-bis(η-allyl)palladium ki te hanga i ētahi atu pūhui kei roto te palladium, tae atu ki ngā matūriki nano palladium me ngā matatini palladium. Ka kitea ngā tono o ēnei pūhui i roto i ngā mara maha, pērā i te whakaterenga, te pūtaiao rauemi, me te hikohiko. I roto i te whakaterenga, ka whakamahia te di-μ-chloro-bis(η-allyl)palladium ki te hanganga o te whānuitanga o ngā ngota waro, tae atu ki ngā rongoā, ngā matū ahuwhenua, me ngā matū motuhake. Ko tōna kaha ki te whakahohe i ngā hononga allylic CH me te whakahaere i tā rātou mahi ka waiho hei taputapu whai hua i roto i te whakawhanaketanga o ngā huarahi hanga hou me te hanga i ngā ngota matatini. I roto i te pūtaiao rauemi, ka whakamahia te di-μ-chloro-bis(η-allyl)palladium ki te whakarite i ngā rauemi kei roto te palladium, pērā i ngā kiriata angiangi me ngā paninga. Ka kitea ngā tono o ēnei rauemi i roto i ngā hikohiko, ngā pūoko, me te whakaterenga. Hei whakarāpopototanga, he matū whakakoi maha ngā mahi a te di-μ-chloro-bis(η-allyl)palladium e kitea ana ngā tono i roto i te whakaterenga, te pūtaiao rauemi, me ētahi atu mara. Ko tōna kaha ki te whakahohe me te whakahaere i ngā tauhohenga matū maha ka waiho hei taputapu whai hua i roto i te whakawhanaketanga o ngā huarahi hanga whai hua me te pumau. Ka horapa tōna pānga ki te whakaputa matū, rauemi, me ngā rongoā whai hua, ka waiho hei wāhanga nui i roto i te rangahau matū hou me ngā tukanga hanga.