kāponāra, kloropāradiuma(1+),(1Z,5Z)-cycloocta-1,5-diene CAS:63936-85-6

Ko te matatini Palladium(II) Chloro [(C8H12)(Cl)Pd] ka hangaia mā te mahi tahi i waenga i te PdCl4 me ngā ngota trans-(1R,5S)-cycloocta-1,5-diene mā roto i ngā hononga dative. Kei roto i te hua ka puta he ligand dienyl kotahi e herea ana ki ia o ngā pokapū whakarewa e whā mā te mahi tahi-eta. He tino pumau te pāmahana o tēnei matatini nā te kaha o ngā kaha i waenga i ngā ngota i roto i te hanganga. Ko tana whakamahinga kei roto i ngā tukanga whakatere e uru ana ki te tauhohenga hononga whakawhiti. Hei tauira, ka āwhina tēnei momo i te hanganga hononga C–C i te wā o te Tauhohenga Hononga Suzuki e uru ana ki te hono i ngā ngota waro sp2 mā te whakamahi i ngā waikawa boronic hei nucleophiles. Ko te hononga hou ka puta mai ka whakarei ake i ngā āhuatanga o ngā rauemi e whakamahia ana i roto i ngā taputapu hiko, ā, ka pai ake te whai hua. Hei tāpiri, ka kitea te whakamahinga o tēnei whakatere i roto i te tauhohenga hononga Sonogashira i reira ka honoa ngā ngota sp mā te whakamahi i ngā alkynes whakamutunga ka arahi ki te hanganga o te hononga C–C, ā, ka hangaia he rōpū mahi hou he tono pea ki ngā mara maha tae atu ki te hanga rongoā me te pūtaiao rauemi.