bromotris(triphenylphosphine)rhodium(I) CAS:14973-89-8

E whakamahia ana te whakakōkī a Wilkinson i roto i te whānuitanga o ngā panonitanga matū, tae atu ki te hauwai, te hydrosilylation, me ngā tauhohenga hydroformylation. E whakamahia ana hoki i roto i te hanga matū pai, ngā rongoā, me ngā rauemi matatau. Nā te kaha o te whakakōkī ki te whakahaere i ngā tukanga whakakōkī whiriwhiri me te whai hua kua waiho hei taputapu nui i roto i te whakawhanaketanga o ngā tikanga hanga hou me te hanga hua matū whai hua.

Ko tētahi o ngā whakamahinga nui o te whakakōkī a Wilkinson ko te hanga i ngā aldehyde rārangi mā te tauhohenga hydroformylation. Ka whakatairangahia e te whakakōkī te tāpiri whiriwhiri o te hauota waro me te hauwai ki te olefin, ka hua ake te hanganga o te aldehyde. He whānuitia te whakamahinga o tēnei tauhohenga i roto i te hanga i ngā mea hanga kirihou, ngā hopi horoi, me ētahi atu matū ahumahi nui.

Ka whakamahia hoki te whakakorikori a Wilkinson i roto i te hanganga o ngā hua taiao matatini me ngā takawaenga rongoā. Nā ōna āhuatanga ahurei me tōna kaha tauhohenga ka waiho hei taputapu whai hua mō te whakatairanga i ngā momo panoni matū. Hei tāpiri, ka whakamahia i roto i te hanga o ngā matū motuhake, pērā i ngā ligands chiral, me ngā rauemi matatau, pērā i ngā polymers kawe hiko.

I te nuinga o te wā, he matū maha ngā whakamahinga o te Bromotris(triphenylphosphine)rhodium(I) arā, te Wilkinson's catalyst, he nui ngā whakamahinga i roto i te hanga matū waro, te pūtaiao rauemi, me ngā tukanga matū ahumahi. Ka horapa atu ōna whakamahinga pea ki te whanaketanga o ngā pākahiko me ngā pūtau wahie mahi-teitei, he mea nui te pumau me te mahi i ngā pāmahana teitei. Kāore e taea te whakanui rawa i te hiranga o te matū i roto i te mara o te matū waro me te hanga matū ahumahi.